Example: Orbital dependent DFTB: Excitations

Download SP_LR-TDDFTB_ldep.run

#!/bin/sh

echo 'SINGLET-SINGLET (atomic)'

AMS_JOBNAME=SS_atomic $AMSBIN/ams << eor

Task SinglePoint

System
    Atoms
        C       0.81279382      -0.19089242      -7.80488100
        H       5.07095595       1.79589101      -2.49503084
        O      -4.34169576       0.18496986       6.16216037
        H       0.65114558      -2.34332052       3.04942157
        H      -3.72094001      -0.30746453      10.65629162
        C      -5.57421344      -4.70045219       5.73919974
        O      -1.36633817       0.16493071       6.55850374
        H      -1.46686146      -1.86573607      -2.18086178
        C      -3.01691915       1.21584087       8.51312360
        H       0.85684819       0.38891329      -5.92035442
        H      -0.85768102      -0.39560272       5.91987385
        C       4.58793450       0.45500454      -7.38543703
        C      -3.96886809       0.03106136       8.54450871
        H      -3.33250841       1.95291681       9.26711187
        C       3.92209138      -0.59739278      -2.62315330
        C       1.59592218      -0.78493633      -8.81907146
        C       5.37967772       1.61610989      -7.38157700
        H      -3.06208979       1.69077468       7.52509148
        H       3.33153483      -1.95208262      -9.27107004
        H      -5.94850232      -1.45420297       5.29308601
        H      -1.63880964       1.21218459      -4.01748238
        C       5.59481994       2.26846676      -8.60056436
        C      -5.08388814      -3.39466282       5.62101538
        C       1.05877651      -0.90567994     -10.10253961
        H      -6.26086371      -5.15389973      -0.52026711
        C      -3.69329118      -0.44136733       1.61892397
        O      -2.12246826       0.96951335       0.48734843
        H      -3.36468025      -5.09261646       1.88651583
        H       3.06148271      -1.69152499      -7.52879231
        H       3.17373326      -1.41052238      -2.65483607
        N      -4.93118484       0.57668964       3.42288416
        C       5.02671217       1.78315021      -9.77819438
        C      -2.76322583      -0.21060941       0.58045389
        C       1.61310315       4.08163625      -4.15853296
        H       1.65781749      -1.38443872     -10.88135435
        H       5.20362845       2.30053217     -10.72284683
        N       0.98411405      -0.08507509       1.63291837
        C      -0.11811043       0.25869794      -2.77564955
        H      -6.45048439      -5.05126436       1.93188479
        H       1.59815263       3.20254199      -3.50183331
        H       1.34234482      -0.41208751       6.12452565
        H       1.63737674      -1.21173256       4.01945340
        C       4.20911444       0.65414989      -9.74493762
        H       6.57696147       4.84639419      -6.15450696
        C      -0.21818699      -0.42562635     -10.40106016
        C       5.70951738       4.20198950       0.53163316
        H       3.72582808       0.30473367     -10.65974126
        H       1.30002230       4.95753032      -3.56997865
        C      -5.38332193       1.10327004       5.76258524
        O       2.11876506      -0.96761719      -0.48368602
        H       3.36747987       5.09257434      -1.88669707
        C       3.96955931      -0.03154911      -8.54709739
        H      -5.45202800       1.91756888       6.50354887
        H      -0.05604443      -0.66172821      -3.38565283
        C      -1.29259172       1.02692065      -7.03188178
        C       4.92598760       4.02834229      -0.78640963
        H       5.41810069       4.00816916      -2.92592937
        H       0.62681991       0.54013154      11.40524357
        N       4.92387904      -0.57709179      -3.42327889
        H      -6.67262735      -3.28997925       1.88188980
        C      -5.01964339       1.65230714       4.39464527
        N      -0.98529210       0.08880229      -1.62845425
        C       0.96153143      -0.19336875       9.39922574
        H      -2.32333946       1.12272724      -7.40204855
        H       0.89745958       0.50420958      -2.43123110
        C      -2.52759360      -1.24514953      -0.37160649
        C      -4.16508398      -2.69707260       0.74479053
        H       1.95792265      -0.58228753       9.62376812
        H      -4.08676441       2.24629054       4.46107261
        H       6.43082358       3.38289578       0.66634506
        H       5.82384519      -2.33703188      -4.09740481
        H      -5.83676722       2.33355915       4.09698464
        C      -3.92859324       0.59805505       2.62379415
        C       0.46851796      -0.32472735       8.09496128
        C      -0.81292062       0.18985987       7.80374992
        C      -4.37031926      -1.67149537       1.67363244
        C      -1.61111027      -4.08066448       4.15769794
        H      -3.18127053       1.41209360       2.65618469
        C      -1.59618119       0.78622700       8.81666658
        C      -3.22571504      -2.45726125      -0.26496047
        C      -0.03721842      -2.64149792       5.57203231
        H       6.45378047       5.04688468      -1.93244382
        C      -1.05947475       0.90972314      10.10003828
        H      -0.62806832      -0.53344921     -11.40625539
        H       6.26468464       5.15196874       0.51871132
        H      -1.59669820      -3.20085654       3.50197697
        H      -1.65873209       1.39040088      10.87751570
        C       0.76170014      -2.41223156       6.70387740
        C      -0.96223359       0.19573796      -9.39859424
        H      -6.57418468      -4.84847602       6.15445239
        C       0.21729712       0.43018409      10.40014258
        H      -3.02101125      -3.22412477      -1.01674298
        H      -1.33836424       0.41028647      -6.12174251
        H      -1.95871363       0.58505816      -9.62203947
        C       0.99557164      -3.48608765       7.57009940
        C       2.52728814       1.24669288       0.37476371
        H      -1.29763246      -4.95571538       3.56810592
        C       5.91215643       2.21280288      -6.08973566
        C      -0.46874333       0.32431833      -8.09425711
        C       3.22697000       2.45791773       0.26752851
        H       6.19838453       3.17876306      -8.61634613
        H       1.60525462      -3.32686188       8.46233319
        H       5.04370683       4.21405615       1.40646415
        H       3.02419610       3.22494895       1.01966091
        C       0.03796998       2.64154211      -5.57021148
        C       1.29391356      -1.02858260       7.03463312
        H      -6.94337647      -2.55729410       6.25033158
        C       0.44422052      -4.74079106       7.31190581
        C      -0.76019298       2.41089752      -6.70235581
        O      -0.30854601      -1.55602015       4.72689111
        C      -5.70709602      -4.20307659      -0.53194180
        C       3.92154498       5.18836628      -0.94315623
        C      -0.99252733       3.48334068      -7.57075461
        H       5.94851729       1.45248334      -5.29512213
        O      -3.23388160      -1.97990720       4.89463888
        H       0.63641924      -5.57147390       7.99331049
        H      -1.60151250       3.32281756      -8.46323999
        C       5.37718603      -1.10386498      -5.76265521
        C       3.68958071       0.44168957      -1.61727297
        H      -4.45119723      -6.15159749       0.95621376
        C      -0.44029160       4.73806913      -7.31466302
        H      -3.79047474      -1.23510905       5.24022747
        H      -6.42953925      -3.38488638      -0.66602236
        C       2.76065892       0.21188975      -0.57755797
        H      -0.63125189       5.56756528      -7.99785314
        C      -0.37619636      -4.92848081       6.20030574
        H       2.32363204      -1.12532089       7.40739960
        H      -6.19333565      -3.18218232       8.61380622
        C       0.37977422       4.92707746      -6.20301510
        C      -0.62330686       1.41385499      -3.63375315
        H       5.44526365      -1.91794390      -6.50389777
        H      -0.84603671      -5.89907747       6.02769899
        H       0.85074323       5.89743958      -6.03213250
        H       6.94435956       2.55526827      -6.25170134
        H       4.45511515       6.15074627      -0.95680824
        H      -5.07444981      -1.79709374       2.49486194
        C       0.64209808       3.88039463      -5.31002856
        C      -0.64007530      -3.88038447       5.30939434
        H      -5.41692966      -4.01081395       2.92588066
        H      -0.65579031       2.34681310      -3.04768782
        C       3.79761163       3.20232022      -5.07690932
        C      -3.91857929      -5.18868521       0.94289180
        C      -5.91142065      -2.21425858       6.08792264
        C      -3.79656900      -3.20281743       5.07502995
        C       3.02092796       4.30891399      -4.66697576
        C       4.16519226       2.69671733      -0.74350579
        H      -6.35193486       0.57780531       5.72398567
        C      -4.58861684      -0.45480589       7.38332328
        C       3.55447069       5.59373051      -4.79121698
        C       5.00971521      -1.65242908      -4.39564865
        C       4.36776079       1.67112262      -1.67288393
        H       6.34696806      -0.58066583      -5.72209568
        H       2.95800170       6.44665309      -4.45743689
        C      -3.01881386      -4.30896131       4.66601867
        C      -5.37863287      -1.61713107       7.37944408
        H      -3.19524634      -5.21394510       0.11518976
        C       4.82895730       5.79998572      -5.32277400
        C       5.92123014       4.08538851      -1.95322332
        C      -5.91969598      -4.08879523       1.95306303
        C      -5.59119031      -2.27093964       8.59813012
        H       5.23641015       6.80821376      -5.40846166
        C      -3.55114085      -5.59417826       4.79140898
        C      -4.92424440      -4.02961195       0.78653208
        C      -1.60888032      -1.03118918      -1.46946159
        C       5.57678188       4.69894843      -5.73953640
        O       0.30792351       1.55817533      -4.72234841
        H      -5.04089930      -4.21310846      -1.40650801
        H       3.19829313       5.21450999      -0.11539003
        H      -2.95396593      -6.44685493       4.45827526
        C       0.62107613      -1.41110213       3.63669716
        O       3.23393255       1.97982570      -4.89735589
        C       1.60923028       1.03399767       1.47346350
        O       4.33848133      -0.18282864      -6.16375879
        C      -5.02194271      -1.78615195       9.77540439
        H       4.07470090      -2.24285276      -4.46378030
        H       1.46939706       1.86861800       2.18521111
        H       3.78928004       1.23433567      -5.24433158
        C      -4.82536099      -5.80111641       5.32332451
        C       5.08519491       3.39352371      -5.62257098
        C       0.11730322      -0.25386051       2.78062472
        H       6.67266617       3.28517127      -1.88201051
        H      -5.19673746      -2.30474679      10.71978984
        C       3.01657412      -1.21552394      -8.51632426
        H       0.05797623       0.66601530       3.39171136
        O       1.36660360      -0.16880782      -6.55959668
        H      -5.23189059      -6.80964319       5.40983229
        C      -4.20556541      -0.65628284       9.74197413
        H      -0.89911822      -0.49654458       2.43669069
        H      -1.52529996       0.88966309      -0.35559018
        H       1.52209394      -0.88701370       0.35943608
    End
End

Engine DFTB
   Model SCC-DFTB
   ResourcesDir DFTB.org/mio-1-1
   SCC
      OrbitalDependent false
   End
   Properties
       Excitations
           SingleOrbTrans
               Filter
                   OSMin 0.0001
               End
               PrintLowest 50
           End
           TDDFTB
               Calc singlet
               Lowest 20
               Print evcontribs
           End
       End
   End
EndEngine

eor


echo 'SINGLET-SINGLET (l-dependent)'

AMS_JOBNAME=SS_ldep $AMSBIN/ams << eor

Task SinglePoint

System
    Atoms
        C       0.81279382      -0.19089242      -7.80488100
        H       5.07095595       1.79589101      -2.49503084
        O      -4.34169576       0.18496986       6.16216037
        H       0.65114558      -2.34332052       3.04942157
        H      -3.72094001      -0.30746453      10.65629162
        C      -5.57421344      -4.70045219       5.73919974
        O      -1.36633817       0.16493071       6.55850374
        H      -1.46686146      -1.86573607      -2.18086178
        C      -3.01691915       1.21584087       8.51312360
        H       0.85684819       0.38891329      -5.92035442
        H      -0.85768102      -0.39560272       5.91987385
        C       4.58793450       0.45500454      -7.38543703
        C      -3.96886809       0.03106136       8.54450871
        H      -3.33250841       1.95291681       9.26711187
        C       3.92209138      -0.59739278      -2.62315330
        C       1.59592218      -0.78493633      -8.81907146
        C       5.37967772       1.61610989      -7.38157700
        H      -3.06208979       1.69077468       7.52509148
        H       3.33153483      -1.95208262      -9.27107004
        H      -5.94850232      -1.45420297       5.29308601
        H      -1.63880964       1.21218459      -4.01748238
        C       5.59481994       2.26846676      -8.60056436
        C      -5.08388814      -3.39466282       5.62101538
        C       1.05877651      -0.90567994     -10.10253961
        H      -6.26086371      -5.15389973      -0.52026711
        C      -3.69329118      -0.44136733       1.61892397
        O      -2.12246826       0.96951335       0.48734843
        H      -3.36468025      -5.09261646       1.88651583
        H       3.06148271      -1.69152499      -7.52879231
        H       3.17373326      -1.41052238      -2.65483607
        N      -4.93118484       0.57668964       3.42288416
        C       5.02671217       1.78315021      -9.77819438
        C      -2.76322583      -0.21060941       0.58045389
        C       1.61310315       4.08163625      -4.15853296
        H       1.65781749      -1.38443872     -10.88135435
        H       5.20362845       2.30053217     -10.72284683
        N       0.98411405      -0.08507509       1.63291837
        C      -0.11811043       0.25869794      -2.77564955
        H      -6.45048439      -5.05126436       1.93188479
        H       1.59815263       3.20254199      -3.50183331
        H       1.34234482      -0.41208751       6.12452565
        H       1.63737674      -1.21173256       4.01945340
        C       4.20911444       0.65414989      -9.74493762
        H       6.57696147       4.84639419      -6.15450696
        C      -0.21818699      -0.42562635     -10.40106016
        C       5.70951738       4.20198950       0.53163316
        H       3.72582808       0.30473367     -10.65974126
        H       1.30002230       4.95753032      -3.56997865
        C      -5.38332193       1.10327004       5.76258524
        O       2.11876506      -0.96761719      -0.48368602
        H       3.36747987       5.09257434      -1.88669707
        C       3.96955931      -0.03154911      -8.54709739
        H      -5.45202800       1.91756888       6.50354887
        H      -0.05604443      -0.66172821      -3.38565283
        C      -1.29259172       1.02692065      -7.03188178
        C       4.92598760       4.02834229      -0.78640963
        H       5.41810069       4.00816916      -2.92592937
        H       0.62681991       0.54013154      11.40524357
        N       4.92387904      -0.57709179      -3.42327889
        H      -6.67262735      -3.28997925       1.88188980
        C      -5.01964339       1.65230714       4.39464527
        N      -0.98529210       0.08880229      -1.62845425
        C       0.96153143      -0.19336875       9.39922574
        H      -2.32333946       1.12272724      -7.40204855
        H       0.89745958       0.50420958      -2.43123110
        C      -2.52759360      -1.24514953      -0.37160649
        C      -4.16508398      -2.69707260       0.74479053
        H       1.95792265      -0.58228753       9.62376812
        H      -4.08676441       2.24629054       4.46107261
        H       6.43082358       3.38289578       0.66634506
        H       5.82384519      -2.33703188      -4.09740481
        H      -5.83676722       2.33355915       4.09698464
        C      -3.92859324       0.59805505       2.62379415
        C       0.46851796      -0.32472735       8.09496128
        C      -0.81292062       0.18985987       7.80374992
        C      -4.37031926      -1.67149537       1.67363244
        C      -1.61111027      -4.08066448       4.15769794
        H      -3.18127053       1.41209360       2.65618469
        C      -1.59618119       0.78622700       8.81666658
        C      -3.22571504      -2.45726125      -0.26496047
        C      -0.03721842      -2.64149792       5.57203231
        H       6.45378047       5.04688468      -1.93244382
        C      -1.05947475       0.90972314      10.10003828
        H      -0.62806832      -0.53344921     -11.40625539
        H       6.26468464       5.15196874       0.51871132
        H      -1.59669820      -3.20085654       3.50197697
        H      -1.65873209       1.39040088      10.87751570
        C       0.76170014      -2.41223156       6.70387740
        C      -0.96223359       0.19573796      -9.39859424
        H      -6.57418468      -4.84847602       6.15445239
        C       0.21729712       0.43018409      10.40014258
        H      -3.02101125      -3.22412477      -1.01674298
        H      -1.33836424       0.41028647      -6.12174251
        H      -1.95871363       0.58505816      -9.62203947
        C       0.99557164      -3.48608765       7.57009940
        C       2.52728814       1.24669288       0.37476371
        H      -1.29763246      -4.95571538       3.56810592
        C       5.91215643       2.21280288      -6.08973566
        C      -0.46874333       0.32431833      -8.09425711
        C       3.22697000       2.45791773       0.26752851
        H       6.19838453       3.17876306      -8.61634613
        H       1.60525462      -3.32686188       8.46233319
        H       5.04370683       4.21405615       1.40646415
        H       3.02419610       3.22494895       1.01966091
        C       0.03796998       2.64154211      -5.57021148
        C       1.29391356      -1.02858260       7.03463312
        H      -6.94337647      -2.55729410       6.25033158
        C       0.44422052      -4.74079106       7.31190581
        C      -0.76019298       2.41089752      -6.70235581
        O      -0.30854601      -1.55602015       4.72689111
        C      -5.70709602      -4.20307659      -0.53194180
        C       3.92154498       5.18836628      -0.94315623
        C      -0.99252733       3.48334068      -7.57075461
        H       5.94851729       1.45248334      -5.29512213
        O      -3.23388160      -1.97990720       4.89463888
        H       0.63641924      -5.57147390       7.99331049
        H      -1.60151250       3.32281756      -8.46323999
        C       5.37718603      -1.10386498      -5.76265521
        C       3.68958071       0.44168957      -1.61727297
        H      -4.45119723      -6.15159749       0.95621376
        C      -0.44029160       4.73806913      -7.31466302
        H      -3.79047474      -1.23510905       5.24022747
        H      -6.42953925      -3.38488638      -0.66602236
        C       2.76065892       0.21188975      -0.57755797
        H      -0.63125189       5.56756528      -7.99785314
        C      -0.37619636      -4.92848081       6.20030574
        H       2.32363204      -1.12532089       7.40739960
        H      -6.19333565      -3.18218232       8.61380622
        C       0.37977422       4.92707746      -6.20301510
        C      -0.62330686       1.41385499      -3.63375315
        H       5.44526365      -1.91794390      -6.50389777
        H      -0.84603671      -5.89907747       6.02769899
        H       0.85074323       5.89743958      -6.03213250
        H       6.94435956       2.55526827      -6.25170134
        H       4.45511515       6.15074627      -0.95680824
        H      -5.07444981      -1.79709374       2.49486194
        C       0.64209808       3.88039463      -5.31002856
        C      -0.64007530      -3.88038447       5.30939434
        H      -5.41692966      -4.01081395       2.92588066
        H      -0.65579031       2.34681310      -3.04768782
        C       3.79761163       3.20232022      -5.07690932
        C      -3.91857929      -5.18868521       0.94289180
        C      -5.91142065      -2.21425858       6.08792264
        C      -3.79656900      -3.20281743       5.07502995
        C       3.02092796       4.30891399      -4.66697576
        C       4.16519226       2.69671733      -0.74350579
        H      -6.35193486       0.57780531       5.72398567
        C      -4.58861684      -0.45480589       7.38332328
        C       3.55447069       5.59373051      -4.79121698
        C       5.00971521      -1.65242908      -4.39564865
        C       4.36776079       1.67112262      -1.67288393
        H       6.34696806      -0.58066583      -5.72209568
        H       2.95800170       6.44665309      -4.45743689
        C      -3.01881386      -4.30896131       4.66601867
        C      -5.37863287      -1.61713107       7.37944408
        H      -3.19524634      -5.21394510       0.11518976
        C       4.82895730       5.79998572      -5.32277400
        C       5.92123014       4.08538851      -1.95322332
        C      -5.91969598      -4.08879523       1.95306303
        C      -5.59119031      -2.27093964       8.59813012
        H       5.23641015       6.80821376      -5.40846166
        C      -3.55114085      -5.59417826       4.79140898
        C      -4.92424440      -4.02961195       0.78653208
        C      -1.60888032      -1.03118918      -1.46946159
        C       5.57678188       4.69894843      -5.73953640
        O       0.30792351       1.55817533      -4.72234841
        H      -5.04089930      -4.21310846      -1.40650801
        H       3.19829313       5.21450999      -0.11539003
        H      -2.95396593      -6.44685493       4.45827526
        C       0.62107613      -1.41110213       3.63669716
        O       3.23393255       1.97982570      -4.89735589
        C       1.60923028       1.03399767       1.47346350
        O       4.33848133      -0.18282864      -6.16375879
        C      -5.02194271      -1.78615195       9.77540439
        H       4.07470090      -2.24285276      -4.46378030
        H       1.46939706       1.86861800       2.18521111
        H       3.78928004       1.23433567      -5.24433158
        C      -4.82536099      -5.80111641       5.32332451
        C       5.08519491       3.39352371      -5.62257098
        C       0.11730322      -0.25386051       2.78062472
        H       6.67266617       3.28517127      -1.88201051
        H      -5.19673746      -2.30474679      10.71978984
        C       3.01657412      -1.21552394      -8.51632426
        H       0.05797623       0.66601530       3.39171136
        O       1.36660360      -0.16880782      -6.55959668
        H      -5.23189059      -6.80964319       5.40983229
        C      -4.20556541      -0.65628284       9.74197413
        H      -0.89911822      -0.49654458       2.43669069
        H      -1.52529996       0.88966309      -0.35559018
        H       1.52209394      -0.88701370       0.35943608
    End
End

Engine DFTB
   Model SCC-DFTB
   ResourcesDir DFTB.org/mio-1-1
   SCC
      OrbitalDependent true
   End
   Properties
       Excitations
           SingleOrbTrans
               Filter
                   OSMin 0.0001
               End
               printlowest 50
           End
           TDDFTB
               Calc singlet
               Lowest 20
               Print evcontribs
           End
       End
   End
EndEngine

eor


echo 'SINGLET-TRIPLET (atomic)'

AMS_JOBNAME=ST_atomic $AMSBIN/ams << eor

Task SinglePoint

System
    Atoms
        C       0.81279382      -0.19089242      -7.80488100
        H       5.07095595       1.79589101      -2.49503084
        O      -4.34169576       0.18496986       6.16216037
        H       0.65114558      -2.34332052       3.04942157
        H      -3.72094001      -0.30746453      10.65629162
        C      -5.57421344      -4.70045219       5.73919974
        O      -1.36633817       0.16493071       6.55850374
        H      -1.46686146      -1.86573607      -2.18086178
        C      -3.01691915       1.21584087       8.51312360
        H       0.85684819       0.38891329      -5.92035442
        H      -0.85768102      -0.39560272       5.91987385
        C       4.58793450       0.45500454      -7.38543703
        C      -3.96886809       0.03106136       8.54450871
        H      -3.33250841       1.95291681       9.26711187
        C       3.92209138      -0.59739278      -2.62315330
        C       1.59592218      -0.78493633      -8.81907146
        C       5.37967772       1.61610989      -7.38157700
        H      -3.06208979       1.69077468       7.52509148
        H       3.33153483      -1.95208262      -9.27107004
        H      -5.94850232      -1.45420297       5.29308601
        H      -1.63880964       1.21218459      -4.01748238
        C       5.59481994       2.26846676      -8.60056436
        C      -5.08388814      -3.39466282       5.62101538
        C       1.05877651      -0.90567994     -10.10253961
        H      -6.26086371      -5.15389973      -0.52026711
        C      -3.69329118      -0.44136733       1.61892397
        O      -2.12246826       0.96951335       0.48734843
        H      -3.36468025      -5.09261646       1.88651583
        H       3.06148271      -1.69152499      -7.52879231
        H       3.17373326      -1.41052238      -2.65483607
        N      -4.93118484       0.57668964       3.42288416
        C       5.02671217       1.78315021      -9.77819438
        C      -2.76322583      -0.21060941       0.58045389
        C       1.61310315       4.08163625      -4.15853296
        H       1.65781749      -1.38443872     -10.88135435
        H       5.20362845       2.30053217     -10.72284683
        N       0.98411405      -0.08507509       1.63291837
        C      -0.11811043       0.25869794      -2.77564955
        H      -6.45048439      -5.05126436       1.93188479
        H       1.59815263       3.20254199      -3.50183331
        H       1.34234482      -0.41208751       6.12452565
        H       1.63737674      -1.21173256       4.01945340
        C       4.20911444       0.65414989      -9.74493762
        H       6.57696147       4.84639419      -6.15450696
        C      -0.21818699      -0.42562635     -10.40106016
        C       5.70951738       4.20198950       0.53163316
        H       3.72582808       0.30473367     -10.65974126
        H       1.30002230       4.95753032      -3.56997865
        C      -5.38332193       1.10327004       5.76258524
        O       2.11876506      -0.96761719      -0.48368602
        H       3.36747987       5.09257434      -1.88669707
        C       3.96955931      -0.03154911      -8.54709739
        H      -5.45202800       1.91756888       6.50354887
        H      -0.05604443      -0.66172821      -3.38565283
        C      -1.29259172       1.02692065      -7.03188178
        C       4.92598760       4.02834229      -0.78640963
        H       5.41810069       4.00816916      -2.92592937
        H       0.62681991       0.54013154      11.40524357
        N       4.92387904      -0.57709179      -3.42327889
        H      -6.67262735      -3.28997925       1.88188980
        C      -5.01964339       1.65230714       4.39464527
        N      -0.98529210       0.08880229      -1.62845425
        C       0.96153143      -0.19336875       9.39922574
        H      -2.32333946       1.12272724      -7.40204855
        H       0.89745958       0.50420958      -2.43123110
        C      -2.52759360      -1.24514953      -0.37160649
        C      -4.16508398      -2.69707260       0.74479053
        H       1.95792265      -0.58228753       9.62376812
        H      -4.08676441       2.24629054       4.46107261
        H       6.43082358       3.38289578       0.66634506
        H       5.82384519      -2.33703188      -4.09740481
        H      -5.83676722       2.33355915       4.09698464
        C      -3.92859324       0.59805505       2.62379415
        C       0.46851796      -0.32472735       8.09496128
        C      -0.81292062       0.18985987       7.80374992
        C      -4.37031926      -1.67149537       1.67363244
        C      -1.61111027      -4.08066448       4.15769794
        H      -3.18127053       1.41209360       2.65618469
        C      -1.59618119       0.78622700       8.81666658
        C      -3.22571504      -2.45726125      -0.26496047
        C      -0.03721842      -2.64149792       5.57203231
        H       6.45378047       5.04688468      -1.93244382
        C      -1.05947475       0.90972314      10.10003828
        H      -0.62806832      -0.53344921     -11.40625539
        H       6.26468464       5.15196874       0.51871132
        H      -1.59669820      -3.20085654       3.50197697
        H      -1.65873209       1.39040088      10.87751570
        C       0.76170014      -2.41223156       6.70387740
        C      -0.96223359       0.19573796      -9.39859424
        H      -6.57418468      -4.84847602       6.15445239
        C       0.21729712       0.43018409      10.40014258
        H      -3.02101125      -3.22412477      -1.01674298
        H      -1.33836424       0.41028647      -6.12174251
        H      -1.95871363       0.58505816      -9.62203947
        C       0.99557164      -3.48608765       7.57009940
        C       2.52728814       1.24669288       0.37476371
        H      -1.29763246      -4.95571538       3.56810592
        C       5.91215643       2.21280288      -6.08973566
        C      -0.46874333       0.32431833      -8.09425711
        C       3.22697000       2.45791773       0.26752851
        H       6.19838453       3.17876306      -8.61634613
        H       1.60525462      -3.32686188       8.46233319
        H       5.04370683       4.21405615       1.40646415
        H       3.02419610       3.22494895       1.01966091
        C       0.03796998       2.64154211      -5.57021148
        C       1.29391356      -1.02858260       7.03463312
        H      -6.94337647      -2.55729410       6.25033158
        C       0.44422052      -4.74079106       7.31190581
        C      -0.76019298       2.41089752      -6.70235581
        O      -0.30854601      -1.55602015       4.72689111
        C      -5.70709602      -4.20307659      -0.53194180
        C       3.92154498       5.18836628      -0.94315623
        C      -0.99252733       3.48334068      -7.57075461
        H       5.94851729       1.45248334      -5.29512213
        O      -3.23388160      -1.97990720       4.89463888
        H       0.63641924      -5.57147390       7.99331049
        H      -1.60151250       3.32281756      -8.46323999
        C       5.37718603      -1.10386498      -5.76265521
        C       3.68958071       0.44168957      -1.61727297
        H      -4.45119723      -6.15159749       0.95621376
        C      -0.44029160       4.73806913      -7.31466302
        H      -3.79047474      -1.23510905       5.24022747
        H      -6.42953925      -3.38488638      -0.66602236
        C       2.76065892       0.21188975      -0.57755797
        H      -0.63125189       5.56756528      -7.99785314
        C      -0.37619636      -4.92848081       6.20030574
        H       2.32363204      -1.12532089       7.40739960
        H      -6.19333565      -3.18218232       8.61380622
        C       0.37977422       4.92707746      -6.20301510
        C      -0.62330686       1.41385499      -3.63375315
        H       5.44526365      -1.91794390      -6.50389777
        H      -0.84603671      -5.89907747       6.02769899
        H       0.85074323       5.89743958      -6.03213250
        H       6.94435956       2.55526827      -6.25170134
        H       4.45511515       6.15074627      -0.95680824
        H      -5.07444981      -1.79709374       2.49486194
        C       0.64209808       3.88039463      -5.31002856
        C      -0.64007530      -3.88038447       5.30939434
        H      -5.41692966      -4.01081395       2.92588066
        H      -0.65579031       2.34681310      -3.04768782
        C       3.79761163       3.20232022      -5.07690932
        C      -3.91857929      -5.18868521       0.94289180
        C      -5.91142065      -2.21425858       6.08792264
        C      -3.79656900      -3.20281743       5.07502995
        C       3.02092796       4.30891399      -4.66697576
        C       4.16519226       2.69671733      -0.74350579
        H      -6.35193486       0.57780531       5.72398567
        C      -4.58861684      -0.45480589       7.38332328
        C       3.55447069       5.59373051      -4.79121698
        C       5.00971521      -1.65242908      -4.39564865
        C       4.36776079       1.67112262      -1.67288393
        H       6.34696806      -0.58066583      -5.72209568
        H       2.95800170       6.44665309      -4.45743689
        C      -3.01881386      -4.30896131       4.66601867
        C      -5.37863287      -1.61713107       7.37944408
        H      -3.19524634      -5.21394510       0.11518976
        C       4.82895730       5.79998572      -5.32277400
        C       5.92123014       4.08538851      -1.95322332
        C      -5.91969598      -4.08879523       1.95306303
        C      -5.59119031      -2.27093964       8.59813012
        H       5.23641015       6.80821376      -5.40846166
        C      -3.55114085      -5.59417826       4.79140898
        C      -4.92424440      -4.02961195       0.78653208
        C      -1.60888032      -1.03118918      -1.46946159
        C       5.57678188       4.69894843      -5.73953640
        O       0.30792351       1.55817533      -4.72234841
        H      -5.04089930      -4.21310846      -1.40650801
        H       3.19829313       5.21450999      -0.11539003
        H      -2.95396593      -6.44685493       4.45827526
        C       0.62107613      -1.41110213       3.63669716
        O       3.23393255       1.97982570      -4.89735589
        C       1.60923028       1.03399767       1.47346350
        O       4.33848133      -0.18282864      -6.16375879
        C      -5.02194271      -1.78615195       9.77540439
        H       4.07470090      -2.24285276      -4.46378030
        H       1.46939706       1.86861800       2.18521111
        H       3.78928004       1.23433567      -5.24433158
        C      -4.82536099      -5.80111641       5.32332451
        C       5.08519491       3.39352371      -5.62257098
        C       0.11730322      -0.25386051       2.78062472
        H       6.67266617       3.28517127      -1.88201051
        H      -5.19673746      -2.30474679      10.71978984
        C       3.01657412      -1.21552394      -8.51632426
        H       0.05797623       0.66601530       3.39171136
        O       1.36660360      -0.16880782      -6.55959668
        H      -5.23189059      -6.80964319       5.40983229
        C      -4.20556541      -0.65628284       9.74197413
        H      -0.89911822      -0.49654458       2.43669069
        H      -1.52529996       0.88966309      -0.35559018
        H       1.52209394      -0.88701370       0.35943608
    End
End

Engine DFTB
   Model SCC-DFTB
   ResourcesDir DFTB.org/mio-1-1
   SCC
      orbitaldependent false
   End
   Properties
       Excitations
           SingleOrbTrans
               Filter
                   OSMin 0.0001
               End
               PrintLowest 50
           End
           TDDFTB
               Calc triplet
               Lowest 20
               Print evcontribs
           End
       End
   End
EndEngine

eor


echo 'SINGLET-TRIPLET (l-dependent)'

AMS_JOBNAME=ST_ldep $AMSBIN/ams << eor

Task SinglePoint

System
    Atoms
        C       0.81279382      -0.19089242      -7.80488100
        H       5.07095595       1.79589101      -2.49503084
        O      -4.34169576       0.18496986       6.16216037
        H       0.65114558      -2.34332052       3.04942157
        H      -3.72094001      -0.30746453      10.65629162
        C      -5.57421344      -4.70045219       5.73919974
        O      -1.36633817       0.16493071       6.55850374
        H      -1.46686146      -1.86573607      -2.18086178
        C      -3.01691915       1.21584087       8.51312360
        H       0.85684819       0.38891329      -5.92035442
        H      -0.85768102      -0.39560272       5.91987385
        C       4.58793450       0.45500454      -7.38543703
        C      -3.96886809       0.03106136       8.54450871
        H      -3.33250841       1.95291681       9.26711187
        C       3.92209138      -0.59739278      -2.62315330
        C       1.59592218      -0.78493633      -8.81907146
        C       5.37967772       1.61610989      -7.38157700
        H      -3.06208979       1.69077468       7.52509148
        H       3.33153483      -1.95208262      -9.27107004
        H      -5.94850232      -1.45420297       5.29308601
        H      -1.63880964       1.21218459      -4.01748238
        C       5.59481994       2.26846676      -8.60056436
        C      -5.08388814      -3.39466282       5.62101538
        C       1.05877651      -0.90567994     -10.10253961
        H      -6.26086371      -5.15389973      -0.52026711
        C      -3.69329118      -0.44136733       1.61892397
        O      -2.12246826       0.96951335       0.48734843
        H      -3.36468025      -5.09261646       1.88651583
        H       3.06148271      -1.69152499      -7.52879231
        H       3.17373326      -1.41052238      -2.65483607
        N      -4.93118484       0.57668964       3.42288416
        C       5.02671217       1.78315021      -9.77819438
        C      -2.76322583      -0.21060941       0.58045389
        C       1.61310315       4.08163625      -4.15853296
        H       1.65781749      -1.38443872     -10.88135435
        H       5.20362845       2.30053217     -10.72284683
        N       0.98411405      -0.08507509       1.63291837
        C      -0.11811043       0.25869794      -2.77564955
        H      -6.45048439      -5.05126436       1.93188479
        H       1.59815263       3.20254199      -3.50183331
        H       1.34234482      -0.41208751       6.12452565
        H       1.63737674      -1.21173256       4.01945340
        C       4.20911444       0.65414989      -9.74493762
        H       6.57696147       4.84639419      -6.15450696
        C      -0.21818699      -0.42562635     -10.40106016
        C       5.70951738       4.20198950       0.53163316
        H       3.72582808       0.30473367     -10.65974126
        H       1.30002230       4.95753032      -3.56997865
        C      -5.38332193       1.10327004       5.76258524
        O       2.11876506      -0.96761719      -0.48368602
        H       3.36747987       5.09257434      -1.88669707
        C       3.96955931      -0.03154911      -8.54709739
        H      -5.45202800       1.91756888       6.50354887
        H      -0.05604443      -0.66172821      -3.38565283
        C      -1.29259172       1.02692065      -7.03188178
        C       4.92598760       4.02834229      -0.78640963
        H       5.41810069       4.00816916      -2.92592937
        H       0.62681991       0.54013154      11.40524357
        N       4.92387904      -0.57709179      -3.42327889
        H      -6.67262735      -3.28997925       1.88188980
        C      -5.01964339       1.65230714       4.39464527
        N      -0.98529210       0.08880229      -1.62845425
        C       0.96153143      -0.19336875       9.39922574
        H      -2.32333946       1.12272724      -7.40204855
        H       0.89745958       0.50420958      -2.43123110
        C      -2.52759360      -1.24514953      -0.37160649
        C      -4.16508398      -2.69707260       0.74479053
        H       1.95792265      -0.58228753       9.62376812
        H      -4.08676441       2.24629054       4.46107261
        H       6.43082358       3.38289578       0.66634506
        H       5.82384519      -2.33703188      -4.09740481
        H      -5.83676722       2.33355915       4.09698464
        C      -3.92859324       0.59805505       2.62379415
        C       0.46851796      -0.32472735       8.09496128
        C      -0.81292062       0.18985987       7.80374992
        C      -4.37031926      -1.67149537       1.67363244
        C      -1.61111027      -4.08066448       4.15769794
        H      -3.18127053       1.41209360       2.65618469
        C      -1.59618119       0.78622700       8.81666658
        C      -3.22571504      -2.45726125      -0.26496047
        C      -0.03721842      -2.64149792       5.57203231
        H       6.45378047       5.04688468      -1.93244382
        C      -1.05947475       0.90972314      10.10003828
        H      -0.62806832      -0.53344921     -11.40625539
        H       6.26468464       5.15196874       0.51871132
        H      -1.59669820      -3.20085654       3.50197697
        H      -1.65873209       1.39040088      10.87751570
        C       0.76170014      -2.41223156       6.70387740
        C      -0.96223359       0.19573796      -9.39859424
        H      -6.57418468      -4.84847602       6.15445239
        C       0.21729712       0.43018409      10.40014258
        H      -3.02101125      -3.22412477      -1.01674298
        H      -1.33836424       0.41028647      -6.12174251
        H      -1.95871363       0.58505816      -9.62203947
        C       0.99557164      -3.48608765       7.57009940
        C       2.52728814       1.24669288       0.37476371
        H      -1.29763246      -4.95571538       3.56810592
        C       5.91215643       2.21280288      -6.08973566
        C      -0.46874333       0.32431833      -8.09425711
        C       3.22697000       2.45791773       0.26752851
        H       6.19838453       3.17876306      -8.61634613
        H       1.60525462      -3.32686188       8.46233319
        H       5.04370683       4.21405615       1.40646415
        H       3.02419610       3.22494895       1.01966091
        C       0.03796998       2.64154211      -5.57021148
        C       1.29391356      -1.02858260       7.03463312
        H      -6.94337647      -2.55729410       6.25033158
        C       0.44422052      -4.74079106       7.31190581
        C      -0.76019298       2.41089752      -6.70235581
        O      -0.30854601      -1.55602015       4.72689111
        C      -5.70709602      -4.20307659      -0.53194180
        C       3.92154498       5.18836628      -0.94315623
        C      -0.99252733       3.48334068      -7.57075461
        H       5.94851729       1.45248334      -5.29512213
        O      -3.23388160      -1.97990720       4.89463888
        H       0.63641924      -5.57147390       7.99331049
        H      -1.60151250       3.32281756      -8.46323999
        C       5.37718603      -1.10386498      -5.76265521
        C       3.68958071       0.44168957      -1.61727297
        H      -4.45119723      -6.15159749       0.95621376
        C      -0.44029160       4.73806913      -7.31466302
        H      -3.79047474      -1.23510905       5.24022747
        H      -6.42953925      -3.38488638      -0.66602236
        C       2.76065892       0.21188975      -0.57755797
        H      -0.63125189       5.56756528      -7.99785314
        C      -0.37619636      -4.92848081       6.20030574
        H       2.32363204      -1.12532089       7.40739960
        H      -6.19333565      -3.18218232       8.61380622
        C       0.37977422       4.92707746      -6.20301510
        C      -0.62330686       1.41385499      -3.63375315
        H       5.44526365      -1.91794390      -6.50389777
        H      -0.84603671      -5.89907747       6.02769899
        H       0.85074323       5.89743958      -6.03213250
        H       6.94435956       2.55526827      -6.25170134
        H       4.45511515       6.15074627      -0.95680824
        H      -5.07444981      -1.79709374       2.49486194
        C       0.64209808       3.88039463      -5.31002856
        C      -0.64007530      -3.88038447       5.30939434
        H      -5.41692966      -4.01081395       2.92588066
        H      -0.65579031       2.34681310      -3.04768782
        C       3.79761163       3.20232022      -5.07690932
        C      -3.91857929      -5.18868521       0.94289180
        C      -5.91142065      -2.21425858       6.08792264
        C      -3.79656900      -3.20281743       5.07502995
        C       3.02092796       4.30891399      -4.66697576
        C       4.16519226       2.69671733      -0.74350579
        H      -6.35193486       0.57780531       5.72398567
        C      -4.58861684      -0.45480589       7.38332328
        C       3.55447069       5.59373051      -4.79121698
        C       5.00971521      -1.65242908      -4.39564865
        C       4.36776079       1.67112262      -1.67288393
        H       6.34696806      -0.58066583      -5.72209568
        H       2.95800170       6.44665309      -4.45743689
        C      -3.01881386      -4.30896131       4.66601867
        C      -5.37863287      -1.61713107       7.37944408
        H      -3.19524634      -5.21394510       0.11518976
        C       4.82895730       5.79998572      -5.32277400
        C       5.92123014       4.08538851      -1.95322332
        C      -5.91969598      -4.08879523       1.95306303
        C      -5.59119031      -2.27093964       8.59813012
        H       5.23641015       6.80821376      -5.40846166
        C      -3.55114085      -5.59417826       4.79140898
        C      -4.92424440      -4.02961195       0.78653208
        C      -1.60888032      -1.03118918      -1.46946159
        C       5.57678188       4.69894843      -5.73953640
        O       0.30792351       1.55817533      -4.72234841
        H      -5.04089930      -4.21310846      -1.40650801
        H       3.19829313       5.21450999      -0.11539003
        H      -2.95396593      -6.44685493       4.45827526
        C       0.62107613      -1.41110213       3.63669716
        O       3.23393255       1.97982570      -4.89735589
        C       1.60923028       1.03399767       1.47346350
        O       4.33848133      -0.18282864      -6.16375879
        C      -5.02194271      -1.78615195       9.77540439
        H       4.07470090      -2.24285276      -4.46378030
        H       1.46939706       1.86861800       2.18521111
        H       3.78928004       1.23433567      -5.24433158
        C      -4.82536099      -5.80111641       5.32332451
        C       5.08519491       3.39352371      -5.62257098
        C       0.11730322      -0.25386051       2.78062472
        H       6.67266617       3.28517127      -1.88201051
        H      -5.19673746      -2.30474679      10.71978984
        C       3.01657412      -1.21552394      -8.51632426
        H       0.05797623       0.66601530       3.39171136
        O       1.36660360      -0.16880782      -6.55959668
        H      -5.23189059      -6.80964319       5.40983229
        C      -4.20556541      -0.65628284       9.74197413
        H      -0.89911822      -0.49654458       2.43669069
        H      -1.52529996       0.88966309      -0.35559018
        H       1.52209394      -0.88701370       0.35943608
    End
End

Engine DFTB
   Model SCC-DFTB
   ResourcesDir DFTB.org/mio-1-1
   SCC
      OrbitalDependent true
   End
   Properties
       Excitations
           SingleOrbTrans
               Filter
                   OSMin 0.0001
               End
               PrintLowest 50
           End
           TDDFTB
               Calc triplet
               Lowest 20
               Print evcontribs
           End
       End
   End
EndEngine

eor