Example: IQA/QTAIM analysis¶
#! /bin/sh
# An IQA/QTAIM analysis is performed to analyze selected interactions
# in formic acid dimer
NSCM=1
export NSCM
AMS_JOBNAME=IQA $AMSBIN/ams <<eor
System
atoms
C -4.777280616716 -2.237679070420 0.027134922119
O -4.316098016052 -1.091055032354 -0.045982864295
O -4.095233471752 -3.376211708158 -0.036303239453
H -5.858352595246 -2.416180987684 0.158163319700
H -3.096816965327 -3.182195213950 -0.161436385033
C -1.043719708731 -1.744256936204 -0.434121365892
O -1.505389993838 -2.890945383925 -0.365122472158
O -1.725417179069 -0.605694491898 -0.367592891810
H -2.724119170709 -0.799847829461 -0.245243925045
H 0.037480148811 -1.565749121998 -0.563863149179
end
end
Task SinglePoint
Engine ADF
title IQA Analysis for (HCOOH)2
IQA
Enabled True
atomstodo 2 5 7 9
print Normal
end
basis
type TZP
core None
end
symmetry NOSYM
xc
dispersion Grimme3
gga BLYP
end
Relativity
Level None
End
EndEngine
eor
# Another IQA analysis for a halogen bonded complex: F-Cl...NH3
# All interactions are calculated - Details printed (verbose mode)
AMS_JOBNAME=IQA2 $AMSBIN/ams <<eor
System
atoms
F 0.000001582319 0.000000000000 -3.410515944395
Cl 0.000001582319 0.000000000000 -1.623156530960
N 0.000001582319 0.000000000000 0.662184762067
H -0.482577891417 0.835852167201 0.991662308171
H -0.482577891417 -0.835852167201 0.991662308171
H 0.965160529792 0.000000000000 0.991662308171
end
end
Task SinglePoint
Engine ADF
title IQA Analysis for F-Cl...NH3
IQA
Enabled True
print Verbose
end
basis
type TZ2P
core None
end
symmetry NOSYM
xc
dispersion Grimme3
gga BLYP
end
Relativity
Level None
End
EndEngine
eor
# IQA analysis for PF5
AMS_JOBNAME=IQA3 "$AMSBIN/ams" << eor
Task SinglePoint
System
Atoms
P 0.0 0.0 0.0
F 0.0 0.0 -1.59029681775
F 1.56093864075 0.0 0.0
F -0.78046932037 1.35181251664 0.0
F 0.0 0.0 1.59029681775
F -0.78046932037 -1.35181251664 0.0
End
End
Engine ADF
Title IQA Analysis PF5
Basis
Type DZP
Core None
End
Symmetry NOSYM
IQA
Enabled Yes
Print Verbose
AtomsToDo 1 3
End
Relativity
Level None
End
EndEngine
eor