Example: Damped Verdet constants: Propene¶
Specify the subkey MAGOPTROT in the AORESPONSE key to calculate the Verdet constant. Here it is specified together with the LIFETIME key, such that the real and imaginary part of the damped Verdet constant will be calculated.
$ADFBIN/adf <<eor
title Propene
ATOMS
C 0.867000 1.441800 3.000000
C 0.849400 2.777300 3.000000
C 2.115500 0.591200 3.000000
H -0.088300 0.909000 3.000000
H -0.085900 3.336500 3.000000
H 1.772400 3.363200 3.000000
H 2.737100 0.793300 2.115200
H 1.876900 -0.479100 3.000000
H 2.737100 0.793300 3.884800
END
basis
type DZP
core None
end
symmetry nosym
allpoints
BeckeGrid
quality good
End
XC
Model SAOP
END
noprint sfo
aoresponse
scf converge 1d-5 iterations 25
frequency 1 0.2 Hartree
ALDA
giao
magoptrot
lifetime 0.007
end
end input
eor